Complexation of Chiral Zinc(II)Porphyrin Tweezer with Chiral Guests: Control, Discrimination and Rationalization of Supramolecular Chirality.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00877
Abstract: A series of 1:1 sandwich complexes consisting of chiral zinc(II) bisporphyrin hosts and a series of chiral guests has been synthesized and has rationalized the underpinning mechanism of chirality transfer in the host-guest supramolecular assemblies.… read more here.
Keywords: chirality; chiral zinc; chiral guests; host ... See more keywords
Construction of a chiral zinc-camphorate framework for enantioselective separation.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01221a
Abstract: A chiral metal-organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid adsorbent, capable of separating a… read more here.
Keywords: framework enantioselective; zinc camphorate; camphorate framework; framework ... See more keywords