Atropisomeric Phosphine Ligands Bearing C-N Axial Chirality: Applications in Enantioselective Suzuki-Miyaura Cross-Coupling Towards the Assembly of Tetra-ortho-Substituted Biaryls.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c06240
Abstract: Biaryl phosphines bearing C(Ar)-C(Ar) axial chirality are commonly known and have been successfully applied in many asymmetric catalyses. Nevertheless, the development of a chiral ligand having an axially chiral C(Ar)-N backbone remains elusive due to… read more here.
Keywords: enantioselective suzuki; bearing axial; applications enantioselective; chirality applications ... See more keywords
Asymmetric interface excited chirality and its applications in reconfiguration.
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DOI: 10.1364/oe.470450
Abstract: In this paper, a chiral excitation method based on the asymmetric interface condition is proposed. The chiral characteristics of the metamaterials are affected by the difference in the environmental parameters of the front and rear… read more here.
Keywords: interface excited; excited chirality; interface; chirality applications ... See more keywords