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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00753
Abstract: We present a central-to-axial chirality conversion strategy for the construction of C-N axially chiral N-arylpyrroles via a gold(I)-catalyzed 5-endo-dig cyclization/dehydration cascade from amino acid derivatives. The reaction exhibits high efficiency on the central-to-axial chirality conversion.…
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Keywords:
axial chirality;
conversion strategy;
chirality conversion;
central axial ... See more keywords