Amplifying the Circularly Polarized Luminescence of CsPbBr3 Nanocrystals by Chiral Metal–Organic Frameworks: In‐Situ Growth, Chiral Assemble, and Chirality Transfer
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202522001
Abstract: Halide perovskites have risen as promising circularly polarized luminescent (CPL) materials for applications in 3D displays, optical anti‐counterfeiting, and information storage. And yet, achieving highly anisotropic CPL emission from achiral halide perovskites remains fraught with… read more here.
Keywords: chirality transfer; mofs; cpl; cspbbr3 ... See more keywords
Spectroscopic investigation on chirality transfer in additive-driven self-assembly of block polymers
Sign Up to like & getrecommendations! Published in 2017 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2017.04.009
Abstract: Abstract Chiral supramolecules prepared by the additive-driven self-assembly of block copolymers provide a facile method to construct helical nanostructures. In this study, we investigated the chiral transfer from chiral tartaric acid to poly(styrene)-b-poly(ethylene oxide) using… read more here.
Keywords: driven self; block; chirality; chirality transfer ... See more keywords
Orientational effects of h-bonding in the chirality transfer from (2R,3R)‑(−)‑2,3-butandiol to polar nematic liquid crystal
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.10.159
Abstract: Abstract The dielectric and orientational properties of solutions of chiral (2R, 3R) - (−) 2,3‑butanediol and its racemic mixture in a liquid-crystalline mixture of alkoxycyanobiphenyls (CB6) were studied. The introduction of the chiral diol leads… read more here.
Keywords: chirality transfer; transfer butandiol; effects bonding; orientational effects ... See more keywords
Unveiling Chirality Transfer between Chiral Centers and Metal Halides in Chiral Organic-Inorganic Hybrid Metal Halides.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c03606
Abstract: Chirality transfer refers to the process in which chiral cations compel the crystallization of the inorganic component into the Sohncke group. Enhancing the chirality of the inorganic component in chiral organic-inorganic hybrid metal halides (OIHMHs)… read more here.
Keywords: chirality transfer; chiral centers; chirality; metal halides ... See more keywords
Chirality Transfer and Asymmetric Catalysis: Two Strategies toward the Enantioselective Formal Total Synthesis of (+)-Gelsenicine.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01974
Abstract: Two strategies are described en route to an enantioselective total synthesis of gelsenicine. One approach centers on a chirality transfer cycloisomerization that ultimately fell short. Separately, an asymmetric catalysis route utilizing bisphosphine-gold-catalyzed cycloisomerization was pursued.… read more here.
Keywords: total synthesis; chirality transfer; two strategies; synthesis gelsenicine ... See more keywords
Molecular-Induced Chirality Transfer to Plasmonic Lattice Modes
Sign Up to like & getrecommendations! Published in 2023 at "ACS Photonics"
DOI: 10.1021/acsphotonics.3c00174
Abstract: Molecular chirality plays fundamental roles in biology. The chiral response of a molecule occurs at a specific spectral position, determined by its molecular structure. This fingerprint can be transferred to other spectral regions via the… read more here.
Keywords: lattice modes; plasmonic lattice; chirality transfer; chirality ... See more keywords
Stereodivergent Chirality Transfer by Noncovalent Control of Disulfide Bonds
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10000
Abstract: Controlling dynamic stereochemistry is an important challenge, as it is not only inherent to protein structure and function but often governs supramolecular systems and self-assembly. Typically, disulfide bonds exhibit stereodivergent behavior in proteins; however, how… read more here.
Keywords: stereodivergent chirality; chirality transfer; disulfide bonds; control disulfide ... See more keywords
Chirality transfer between hexaazamacrocycles in heterodinuclear rare earth complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01318k
Abstract: Both the chiral hexaazamacrocyle L1 based on trans-1,2-diaminocyclohexane and the achiral hexaazamacrocyle L2 based on ethylenediamine form lanthanide(iii) dinuclear μ-hydroxo bridged complexes which have been characterized by NMR and CD spectroscopy. The homodinuclear complexes of… read more here.
Keywords: chirality; chirality transfer; transfer hexaazamacrocycles; hexaazamacrocycles heterodinuclear ... See more keywords
Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c9ra05482k
Abstract: Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess. read more here.
Keywords: chirality transfer; rearrangement silyl; asymmetric retro; brook rearrangement ... See more keywords
“Gear-driven”-type chirality transfer of tetraphenylethene-based supramolecular organic frameworks for peptides in water
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d3sc06349f
Abstract: Chirality transfer for natural chiral biomolecules can reveal the indispensable role of chiral structures in life and can be used to develop the chirality-sensing biomolecular recognition. Here, we report the synthesis and characterization of a… read more here.
Keywords: chirality transfer; driven type; type chirality; chirality ... See more keywords
Multistep Chirality Transfer and Racemization Kinetics of Pillar [5]arenes by Tuning the Halogen Substituents on the Rims
Sign Up to like & getrecommendations! Published in 2024 at "Organic Chemistry Frontiers"
DOI: 10.1039/d4qo01799d
Abstract: Halogen-substituted pillar[5]arenes exhibited hindered hydroquinone subunit flipping, enabling enantioseparation. An enantiopure conformer demonstrated a dissymmetric factor of 0.012 and an enantioselective binding ratio exceeding 1.92. Complexation with L-serine induced an... read more here.
Keywords: chirality transfer; transfer racemization; racemization kinetics; halogen ... See more keywords