Catalytic Asymmetric Allylic Substitution/Isomerization with Central Chirality Transposition.
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DOI: 10.1021/acs.orglett.2c01559
Abstract: We have developed a catalytic asymmetric allylic substitution/isomerization process with central chirality transposition. This process takes advantage of the ambident reactivity of the 2-indole imine methide generated in situ from racemic tertiary indolylmethanols. The use… read more here.
Keywords: allylic substitution; chirality transposition; central chirality; substitution isomerization ... See more keywords