C-H Arylation of Phenanthrene with Trimethylphenylsilane by Pd/o-Chloranil Catalysis: Computational Studies on the Mechanism, Regioselectivity, and Role of o-Chloranil.
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DOI: 10.1021/jacs.7b11260
Abstract: The transition-metal-catalyzed C-H arylation of aromatic hydrocarbons represents a useful and ideal method for the production of biaryls and multiarylated aromatic compounds. We have previously reported the palladium-catalyzed direct C-H arylation of polycyclic aromatic hydrocarbons,… read more here.
Keywords: role chloranil; chloranil; arylation; phenanthrene trimethylphenylsilane ... See more keywords
Synthesis of 2,4-Diarylquinoline Derivatives via Chloranil-Promoted Oxidative Annulation and One-Pot Reaction
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DOI: 10.1055/s-0039-1691740
Abstract: An oxidative annulation for the synthesis of 2,4-diarylquinolines from o-allylanilines is disclosed that uses recyclable reagent Chloranil as the oxidant. The corresponding products are obtained in moderate to excellent yields. Furthermore, a one-pot access to… read more here.
Keywords: annulation; oxidative annulation; chloranil; one pot ... See more keywords