Carbon–Chloride Bond Activation: Ni‐Catalyzed Couplings of Carboxylic Acid With Dichloromethane
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DOI: 10.1002/aoc.70250
Abstract: A Ni‐catalyzed double carbon–chloride bond activation of dichloromethane was achieved, leading to an efficient synthesis of aryl, heteroaryl, alkenyl, alkynyl, and even alkyl diesters from the cross‐couplings of the corresponding carboxylic acid with DCM. This… read more here.
Keywords: chloride bond; bond activation; carbon chloride;
Enantioselective electrochemical carbon-chloride bond cleavage of hexachlorocyclohexanes (HCHs) catalyzed by Mn(III)Cl-phthalocyanine
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2017.09.020
Abstract: Abstract A lipophilic and electron-rich metallophthalocyanine Mn(III)Cl(α,α′-n-OC 5 H 11 ) 8 Pc has been synthesized and characterized. A series of electrochemical experiments demonstrate that the Mn(III)Cl(α,α′-n-OC 5 H 11 ) 8 Pc complex can… read more here.
Keywords: chloride bond; carbon chloride; bond cleavage;