Coordination Variability through Inner-Outer-Sphere Chloride Exchange in Complex Heterometallic Clusters [M2Bi14Cl4][AlCl4]4 and [M2Bi14Cl2][AlCl4]6 (M = Ru, Os).
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04069
Abstract: Five novel heterometallic bismuth-bearing cluster salts within two structural families, monoclinic P21/c α-[M2Bi14Cl4][TrCl4]4 and triclinic P1̅ [M2Bi14Cl2][AlCl4]6 (M = Ru, Os; Tr = Al, Ga), have been discovered via Lewis acidic ionic liquid (LAIL)-assisted synthesis… read more here.
Keywords: sphere chloride; inner outer; m2bi14cl2 alcl4; chloride exchange ... See more keywords