Nonclassical C86 and C88 Chlorofullerenes via Complex Chlorination-Promoted Skeletal Transformations of IPR Isomers of C88 and C96.
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DOI: 10.1021/acs.inorgchem.4c03668
Abstract: Upon high-temperature (340-360 °C) chlorination with VCl4, an isolated-pentagon-rule (IPR) C2-C88(33) fullerene is just chlorinated to C88(33)Cl22 and C88(33)Cl28, but a VCl4/SbCl5 mixture promotes a five-step cage transformation to nonclassical C86(NC2)Cl30 with two heptagons and… read more here.
Keywords: chlorination; chlorination promoted; c86 c88; nonclassical c86 ... See more keywords
Versatility of chlorination-promoted skeletal transformation pathways in C76 fullerene.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00245b
Abstract: We present the synthesis and crystal structure of a new chlorinated non-IPR isomer of C76 fullerene, 18387C76Cl30. The new chloride is formed from IPR-D2-C76via a sequence of chlorination-promoted Stone-Wales rearrangements concurrently with the previously known… read more here.
Keywords: non ipr; chlorination promoted; c76 fullerene; pathways c76 ... See more keywords