Dispersion in Crystal Structures of 1-Chloro-3-aryl-5-trihalomethyl-1λ 4 ,2,4,6-thiatriazines: Towards an Understanding of the Supramolecular Organization of Covalent Thiazyl Chlorides
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DOI: 10.1055/a-2071-4235
Abstract: The syntheses of five new 1-chloro-3-aryl-5-trichloromethyl-1λ4,2,4,6-thiatriazines, aryl = 4-R-C6H4- (R = CH3O, CH3, H, Cl and CF3), are reported with full characterization. Single-crystal X-ray diffraction structure determinations on all, as well as the 5-CF3 analogue… read more here.
Keywords: trihalomethyl thiatriazines; chloro aryl; crystal structures; dispersion crystal ... See more keywords
Synthesis of some novel chloro-/aryl-substituted-5,5-dimethyl-2-cyclohexenones
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DOI: 10.1080/00397911.2020.1723108
Abstract: Abstract Two novel structural isomers: the dihalo-5,5-dimethyl-2-cyclohexenones were synthesized. Regioselective Suzuki-Miyaura cross coupling reaction of the isomers with nine different aryl boronic acids afforded eighteen novel compounds: the 2-aryl-3-chloro-5,5-dimethyl-2-cyclohexenones and the 3-aryl-2-chloro-5,5-dimethyl-2-cyclohexenones in 90–95% yields,… read more here.
Keywords: chloro aryl; synthesis novel; aryl substituted; novel chloro ... See more keywords