A highly efficient TEMPO mediated oxidation of sugar primary alcohols into uronic acids using 1-chloro-1,2-benziodoxol-3(1H)-one at room temperature
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DOI: 10.1016/j.tetlet.2018.05.021
Abstract: Abstract Oxidation of various sugar primary alcohols into corresponding uronic acids was demonstrated using 1-chloro-1,2-benziodoxol-3(1H)-one and TEMPO. The reaction proceeds at room temperature in good to excellent yields. Primary alcohols get oxidized selectively over the… read more here.
Keywords: sugar primary; benziodoxol one; chloro benziodoxol; primary alcohols ... See more keywords
Revisiting 1-chloro-1,2-benziodoxol-3-one: efficient ortho-chlorination of aryls under aqueous conditions
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DOI: 10.1039/c8nj00530c
Abstract: The application of 1-chloro-1,2-benziodoxol-3-one as a powerful chlorinating agent as well as oxidant for aniline derivatives is explored. The amide directing group assisted radical mediated ortho-selective chlorination proceeds in the absence of a radical initiator.… read more here.
Keywords: chlorination; benziodoxol one; chloro benziodoxol; revisiting chloro ... See more keywords