CaBaFx composite as robust catalyst for the pyrolysis of 1-chloro-1,1-difluoroethane to vinylidene fluoride
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DOI: 10.1016/j.catcom.2018.11.011
Abstract: Abstract CaBaFx composites were prepared by a solid-state grinding method with various molar ratios of Ca and Ba and evaluated as catalysts for the pyrolysis of 1-chloro-1,1-difluoroethane (HCFC-142b, CH3CClF2) to vinylidene fluoride (VDF, CH2=CF2). The… read more here.
Keywords: pyrolysis chloro; chloro difluoroethane; vinylidene fluoride; cabafx ... See more keywords
Experimental and DFT Mechanistic Study of Dehydrohalogenation of 1-Chloro-1,1-difluoroethane over Metal Fluorides
Sign Up to like & getrecommendations! Published in 2019 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.9b03976
Abstract: Vinylidene fluoride (VDF) is one of the major fluorinated monomers. Currently, it is produced via the pyrolysis of 1-chloro-1,1-difluoroethane at above 650 °C without any catalyst. Herein, we propo... read more here.
Keywords: dft mechanistic; mechanistic study; chloro; chloro difluoroethane ... See more keywords