Coupling of 1-Chloro-N,N-diisopropylphosphanamine-Based Reagents with Alcohols and Thiosulfonates: A Precise Construction of O-P(O)-S Bonds.
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DOI: 10.1021/acs.orglett.2c01947
Abstract: Herein, we present the first mild, one-step direct synthesis of mixed phosphorothioates through selective generation of O-P(O)-S bonds at rt under additive-free condition. Further, reactions of different model natural products with 1,1-dichloro-N,N-diisopropylphosphanamine helped to present… read more here.
Keywords: diisopropylphosphanamine; coupling chloro; synthesis mixed; chloro diisopropylphosphanamine ... See more keywords