Carboxylative Coupling of Chloromethyl(hetero)arenes with Allyltrimethoxysilane Catalyzed by Palladium Nanoparticles
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DOI: 10.1002/ajoc.201600510
Abstract: The palladium-catalyzed three-component coupling of (chloromethyl)arenes or (chloromethyl)heteroarenes, allytrimethoxysilane, and carbon dioxide (carboxylative Hiyama coupling reaction) was successfully conducted to produce α,β-unsaturated esters in satisfactory to good yields. The carboxylative Hiyama coupling reaction proceeded smoothly… read more here.
Keywords: palladium nanoparticles; carboxylative coupling; coupling chloromethyl; hetero arenes ... See more keywords