Ni-Catalyzed Asymmetric Reductive Alkenylation of α-Chlorosulfones with Vinyl Bromides.
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DOI: 10.1021/acs.orglett.2c00217
Abstract: A nickel-catalyzed enantioconvergent reductive cross-coupling of α-chlorosulfones with vinyl bromides is described here. This strategy enables the enantioselective construction of chiral allylic sulfones from simple α-chlorosulfones and vinyl bromides. The mild reaction conditions lead to… read more here.
Keywords: chlorosulfones vinyl; vinyl bromides; asymmetric reductive; reductive alkenylation ... See more keywords