Reactions of organoplatinum complexes with dimethylamine-borane
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DOI: 10.1039/d0nj03168b
Abstract: The reactions of dimethylamine-borane with platinum(II) or platinum(IV) triflate complexes gave, not the anticipated σ-complexes, but the respective hydridoplatinum complexes. The reaction with [Pt(OTf)Me3(NN)], with NN = 2,2′-bipyridine (bipy) and 4,4′-di-t-butyl-2,2′-bipyridine (bu2bipy), gave the rare… read more here.
Keywords: chmeco2me bipy; dimethylamine borane; hydridoplatinum complexes; bipy ... See more keywords