A Highly Reactive Chromium(V)–Oxo TAML Cation Radical Complex in Electron Transfer and Oxygen Atom Transfer Reactions
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.1c00079
Abstract: We report the synthesis, characterization, and electron-transfer (ET) oxidation reactivity of a chromium(V)–oxo TAML cation radical complex binding Sc3+ ion, {[CrV(O)(TAML•+)]-Sc3+}3+ (2-Sc). Its p... read more here.
Keywords: taml cation; oxo taml; transfer; taml ... See more keywords
Kinetics of chromium(V)-oxo and chromium(IV)-oxo porphyrins: Reactivity and mechanism for sulfoxidation reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of inorganic biochemistry"
DOI: 10.2139/ssrn.4163383
Abstract: In this work, chromium(IV)-oxo porphyrins [CrIV(Por)(O)] (2) (Por = porphyrin) were produced either by oxidation of [CrIII(Por)Cl] (1) with iodobenzene diacetate or visible light photolysis of porphyrin‑chromium(III) chlorates. Subsequent oxidation of 2 with silver perchlorate gave chromium(V)-oxo… read more here.
Keywords: oxo; chromium oxo; oxo porphyrins; porphyrin ... See more keywords