Oxidative Dearomatization and Sigmatropic 1,3-Acyl Shift in Excited State: Aromatics to Embellished cis-Hydrindanes
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DOI: 10.1055/s-0037-1611367
Abstract: A stereoselective synthetic route to embellished cis-hydrindanes from simple aromatic precursors is described. Oxidative dearomatization, ring expansion, and photochemical 1,3-acyl shift are the key features of our approach. Oxidative dearomatization of o-(hydroxymethyl)phenols followed by π4s… read more here.
Keywords: acyl shift; oxidative dearomatization; embellished cis; cis hydrindanes ... See more keywords