Heterocyclic nitrogen donor complexes of aluminium, gallium and indium with weakly coordinating triflate anions
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DOI: 10.1016/j.poly.2021.115367
Abstract: Abstract The reactions of M(OTf)3 (M = Al, Ga, In; OTf = CF3SO3–) with 2,2′:6′,2′’- terpyridyl (terpy) in CH2Cl2 gave mer-[M(OTf)3(terpy)], whilst with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) the products isolated were cis-[M”(OTf)2(bipy)2]OTf (M” = Al, Ga), cis-[In(OTf)(H2O)(bipy)2][OTf]2, cis-[Al(OTf)2(phen)2][OTf]… read more here.
Keywords: otf; triflate anions; cis otf; bipy otf ... See more keywords