Alkyltriflones in the Ramberg-Bäcklund Reaction: An Efficient and Modular Synthesis of gem-Difluoroalkenes.
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DOI: 10.1021/jacs.0c07924
Abstract: The unprecedented synthesis of gem-difluoroalkenes through the Ramberg-Bäcklund reaction of alkyl triflones is described herein. Structurally diverse, fully-substituted gem-difluoroalkenes that are difficult to prepare by other methods can be easily prepared from readily available triflones… read more here.
Keywords: gem; gem difluoroalkenes; cklund reaction; synthesis gem ... See more keywords