Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene
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DOI: 10.1021/acs.orglett.9b02683
Abstract: We present to date the most efficient gram-scale synthesis of triangulene-4,8-dione and 12-hydroxytriangulene-4,8-dione, the precursors of Clar’s hydrocarbon, in overall yields >50%. The direct dihydroprecursors of triangulene, obtained upon reduction of triangulene-4,8-dione, were stabilized in… read more here.
Keywords: gram scale; scale synthesis; triangulene; supramolecular complex ... See more keywords