Synthesis of a new class of cationic Pd(II) complexes with 1,2,3-triazol-5-ylidene ligand and their catalytic application in the conversion of internal alkynes to 1,2-diketones
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DOI: 10.1016/j.jorganchem.2018.02.011
Abstract: Abstract A new class of cationic Pd(II) complexes of the type [Pd(Tz)(Cl)(bipy)]+Cl− and [Pd (Tz)(Cl)(phen)]+Cl− (Tz = 1,4-diaryl-3-methyl-1,2,3-triazol-5-ylidene, bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline) with various wing tip groups were synthesized from the corresponding 1,2,3-triazolium iodide via the corresponding chloro… read more here.
Keywords: new class; cationic complexes; triazol ylidene; conversion ... See more keywords