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Published in 2019 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2019.04.021
Abstract: Abstract Trace dimethoxymethane (DMM) was formed by aldol condensation of formaldehyde with methanol in industrial propene oxide production via a hydrogen peroxide (HPPO process). Probing the behaviour of catalytic action in oxidative cleavage reaction of…
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Keywords:
cleavage;
alkenes h2o2;
catalytic performance;
cleavage alkenes ... See more keywords
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Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b03654
Abstract: This review provides an overview of the recent developments on the oxygen-mediated cleavage of olefins and acetylene derivatives to provide carbonyl and carboxylic compounds. A number of photo, organo, and metal catalysts have been reviewed…
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Keywords:
alkynes carbonyl;
cleavage;
cleavage alkenes;
aerobic cleavage ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05648
Abstract: Herein we report the anaerobic cleavage of alkenes into carbonyl compounds using nitroarenes as oxygen transfer reagents under visible light. This approach serves as a safe and practical alternative to mainstream oxidative cleavage protocols, such…
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Keywords:
cleavage;
oxygen transfer;
using nitroarenes;
cleavage alkenes ... See more keywords