Aromatic C-C Bond Cleavage in a Curved π-System of Aminocorannulene.
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DOI: 10.1021/acs.orglett.3c01107
Abstract: We report a metal- and oxidant-free aromatic C-C bond cleavage in the curved corannulene skeleton. Reaction of 1-aminocorannulene with hydrazonyl chloride generates an amidrazone intermediate that undergoes facile intramolecular proton migrations and ring annulation to… read more here.
Keywords: curved system; bond cleavage; cleavage curved; aromatic bond ... See more keywords