Photothermally promoted cleavage of β-1,4-glycosidic bonds of cellulosic biomass on Ir/HY catalyst under mild conditions
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.06.041
Abstract: Abstract Cellulose represents the major component of the abundant and inedible lignocellulosic biomass on earth. The valorization of cellulose into liquid biofuels and high value-added bio-based chemicals has drawn intensive attentions in recent years. However,… read more here.
Keywords: cleavage glycosidic; glycosidic bonds; cellulosic biomass; mild conditions ... See more keywords
Oxidative Cleavage of Glycosidic Bonds by Synthetic Mimics of Lytic Polysaccharide Monooxygenases.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01312
Abstract: Lytic polysaccharide monooxygenases (LPMOs) cleave polysaccharides through copper-bound oxyl radicals. We report a synthetic mimic of LPMO that uses micelle-stabilized hydrogen bonds to bind a glycan and two molecularly imprinted hydrophobic pockets to accommodate the… read more here.
Keywords: lytic polysaccharide; glycosidic bonds; oxidative cleavage; cleavage glycosidic ... See more keywords