Design of bond-cleavage-induced intramolecular charge transfer emission with dibenzoboroles and their application to ratiometric sensors for discriminating chain lengths of alkanes
Sign Up to like & getrecommendations! Published in 2017 at "Materials Chemistry Frontiers"
DOI: 10.1039/c7qm00350a
Abstract: Dibenzoborole derivatives containing four-coordinated boron were designed to realize emission from the bond-cleavage-induced intramolecular charge transfer (BICT) transition. A series of electron-donating and accepting groups were introduced into dibenzoborole through regioselective bromination and Suzuki–Miyaura coupling… read more here.
Keywords: cleavage induced; intramolecular charge; bond cleavage; induced intramolecular ... See more keywords
Programed Thermoresponsive Polymers with Cleavage-Induced Phase Transition
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DOI: 10.3390/molecules27186082
Abstract: A new programed upper critical solution temperature-type thermoresponsive polymer was developed using water-soluble anionic polymer conjugates derived from polyallylamine and phthalic acid with cleavage-induced phase transition property. Intrinsic charge inversion from anion to cation of… read more here.
Keywords: transition; polymer; phase transition; cleavage induced ... See more keywords