Visible-Light-Mediated C− F Bond Cleavage for the Synthesis of Polyfluorinated Compounds
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00547j
Abstract: Herein, we describe a novel and efficient photo-redox catalytic difluorinated ester radical addition/defluoroalkylation coupling reaction between trifluoroacetic acid derivatives and α-trifluoromethyl alkenes. A series of polyfluorinated compounds were synthesized by... read more here.
Keywords: mediated bond; bond cleavage; polyfluorinated compounds; visible light ... See more keywords
DFT Studies on Ni-Mediated C–F Cleavage for the Synthesis of Cyclopentadiene Derivatives
Sign Up to like & getrecommendations! Published in 2018 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2018.00319
Abstract: Density functional theory calculations have been performed to study the detailed mechanism of Ni-mediated [3+2] cycloaddition of 2-trifluoromethyl-1-alkenes with alkynes via cleavage of two C-F bonds. It was found that the reaction pathway involves oxidative… read more here.
Keywords: studies mediated; dft studies; mediated cleavage; cleavage ... See more keywords