Articles with "clo4 clo4" as a keyword



Formation, reactivity, photorelease, and scavenging of NO in ruthenium nitrosyl complexes

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2019.119360

Abstract: Abstract The two newly designed nitrosyl complexes with Enemark–Feltham notation {RuNO}6 and {RuNO}7 configurations have been isolated as the perchlorate salts in the molecular framework [RuII(dmdptz)(phen)(NO)]n+ (dmdptz: N,N-dimethyl-4,6-di(pyridin-2-yl)-1,3,5-triazin-2-amine and phen: 1,10-phenanthroline) [RuII(dmdptz)(phen)(NO+)](ClO4)3 [4](ClO4)3 and [RuII(dmdptz)(phen)(NO… read more here.

Keywords: dmdptz phen; clo4; clo4 clo4; ruii dmdptz ... See more keywords
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Aryl variation and anion effect on CT-DNA binding and in vitro biological studies of pyridinyl Ag(I) complexes.

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Published in 2020 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2020.111266

Abstract: Synthesis and spectroscopic characterization of five ligands ((E)-2-((pyridin-2-ylmethylene)amino)phenol L1, 2-(pyridin-2-yl)benzo[d]thiazole L2, (E)-N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine L3, (E)-1-(pyridin-2-yl)-N-(p-tolyl)methanimine L4 and (E)-1-(pyridin-2-yl)-N-(thiophen-2-ylmethyl)methanimine L5 along with fifteen silver(I) complexes of L1 - L5, with a general formula [AgL2]+X- (L = Schiff base and… read more here.

Keywords: anion; dna; clo4 clo4; clo4 ... See more keywords
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Indazole-Derived Mono-/Diruthenium and Heterotrinuclear Complexes: Switchable Binding Mode, Electronic Form, and Anion Sensing Events.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c02628

Abstract: The article deals with the newer classes of mononuclear: [(acac)2RuIII(H-Iz)(Iz-)] 1, [(acac)2RuIII(H-Iz)2]ClO4 [1]ClO4/[1']ClO4, and [(bpy)2RuII(H-Iz)(Iz-)]ClO4 [2]ClO4, mixed-valent unsymmetric dinuclear: [(acac)2RuIII(μ-Iz-)2RuII(bpy)2]ClO4 [3]ClO4, and heterotrinuclear: [(acac)2RuIII(μ-Iz-)2MII(μ-Iz-)2RuIII(acac)2] (M = Co:4a, Ni:4b, Cu:4c, and Zn:4d) complexes (H-Iz = indazole,… read more here.

Keywords: clo4; clo4 clo4; anion; acac 2ruiii ... See more keywords
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Unique Metal-Ligand Interplay in Directing Discrete and Polymeric Derivatives of Isomeric Azole-Carboxylate. Varying Electronic Form, C-C Coupling, and Receptor Feature.

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Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c00418

Abstract: This article dealt with the ruthenium and osmium derivatives of isomeric 1H-indazole-3-carboxylic acid/2H-indazole-3-carboxylic acid (H2L1) and 1H-benzimidazole-2-carboxylic acid (H2L2) along with the π-acidic bpy (bpy = 2,2'-bipyridine) and pap (pap = 2-phenylazopyridine) co-ligands. It thus… read more here.

Keywords: clo4; l22; feature; clo4 clo4 ... See more keywords
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Variable electronic structure and spin distribution in bis(2,2'-bipyridine)-metal complexes (M = Ru or Os) of 4,5-dioxido- and 4,5-diimido-pyrene.

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Published in 2021 at "Dalton transactions"

DOI: 10.1039/d1dt00282a

Abstract: The odd-electron compounds [M(bpy)2(L1)](ClO4) M = Ru ([1](ClO4)) or Os ([2](ClO4)), and the even-electron species [M(bpy)2(H2L2)](ClO4)2, M = Ru ([3](ClO4)2) or Os ([4](ClO4)2) were obtained from pyrene-4,5-dione, L1, or 4,5-diaminopyrene, H4L2, and were characterised structurally,… read more here.

Keywords: metal; electronic structure; clo4 clo4; variable electronic ... See more keywords