Isomeric commo‐Ferracarboranes: meso‐, dd/ll‐[PPh3R][commo‐Fe(2,4‐closo‐C2B8H10)2] and Their Bimetal Ferra–Copper Zwitterion Derivatives
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DOI: 10.1002/ejic.201700571
Abstract: The reaction of [Na][C2B8H11] with anhydrous FeCl2 in THF affords a mixture of DD/LL and MESO isomers of anionic paramagnetic commo-ferracarborane [Ph3PR][commo-1,1′-Fe(closo-2,4-C2B8H10)2] (MESO, R = Me: 1a; MESO, Et: 1b; DD/LL, R = Me: 2a;… read more here.
Keywords: commo closo; ferra copper; meso; commo ... See more keywords