The method for synthesis of 2-sulfanyl closo-decaborate anion and its S-alkyl and S-acyl derivatives
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.11.035
Abstract: Abstract A two-stage method for preparation of the sulfanyl derivative of closo-decaborate anion (n-Bu4N)2[2-B10H9SH]2- (1) is worked out. At the first stage, the [2-B10H9SC(NMe2)2]- (2) or the [2-B10H9SCHNMe2]- (3) derivative is obtained by the reaction… read more here.
Keywords: decaborate anion; closo decaborate; sulfanyl;
Decachloro- closo -decaborate anion in copper(II) complexation reactions with N-donor ligands: 35 Cl NQR and X-ray studies
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.02.015
Abstract: Abstract Copper(II) complexation reactions with neutral N-donor ligands (Bipy, Phen, NH3) in the presence of the bulky decachloro-closo-decaborate dianion were studied. Copper(II) complexes can be prepared from copper(II) salts or copper(I) salts by redox reactions… read more here.
Keywords: complexation reactions; donor ligands; copper; closo decaborate ... See more keywords
Alkaline aqueous solution of sodium decahydro-closo-decaborate Na2B10H10 as liquid anodic fuel
Sign Up to like & getrecommendations! Published in 2019 at "Renewable Energy"
DOI: 10.1016/j.renene.2019.05.019
Abstract: Abstract The potential of the decahydro-closo-decaborate anion B10H102− in alkaline aqueous solution as anodic fuel was investigated by using cyclic voltammetry and three different bulk metal electrodes (platinum, gold and silver). The sodium salt NaB10H10… read more here.
Keywords: alkaline aqueous; anodic fuel; closo decaborate; decahydro closo ... See more keywords
Polymorphism of Calcium Decahydrido-closo-decaborate and Characterization of Its Hydrates.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00594
Abstract: Metal closo-borates and their derivatives have shown promise in several fields of application from cancer therapy to solid-state electrolytes partly owing to their stability in aqueous solutions and high thermal stability. We report the synthesis… read more here.
Keywords: decaborate characterization; calcium decahydrido; polymorphism calcium; closo ... See more keywords
New approaches to the functionalization of the 1-carba-closo-decaborate anion.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06395b
Abstract: Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]- at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and… read more here.
Keywords: new approaches; closo decaborate; approaches functionalization; decaborate anion ... See more keywords
Chemistry of Carba-closo-decaborate Anions [CB9H10]– (Review)
Sign Up to like & getrecommendations! Published in 2019 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023619140067
Abstract: The state of the art of the chemistry of carba-closo-decaborate anions [1-CB9H10]− and [2-CB9H10]−, including their synthesis, substitution reactions of hydrogen atoms at carbon and boron atoms, as well as interconversion of various functional derivatives,… read more here.
Keywords: chemistry carba; closo decaborate; anions cb9h10; decaborate anions ... See more keywords
Non-Covalent Interactions in the Crystal Structures of Perbrominated Sulfonium Derivatives of the closo-Decaborate Anion
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms231912022
Abstract: A new series of compounds based on perbrominated disubstituted sulfonium derivatives of the closo-decaborate anion (n-Bu4N)[2-B10Br9SR2] (R = n-Pr, i-Pr, n-Bu, n-C8H17, n-C12H25, n-C18H37) was obtained, characterised by modern physicochemical methods of analysis. According to… read more here.
Keywords: closo decaborate; decaborate anion; non covalent; derivatives closo ... See more keywords