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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c07056
Abstract: Supported metal clusters have reactivities that depend on their nuclearity and structure. Herein, we present a strategy for precisely controlling the nuclearity of platinum clusters and demonstrate their size-dependent restructuring behavior and catalytic properties. The…
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Keywords:
dependent restructuring;
restructuring;
cluster catalysts;
size dependent ... See more keywords
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Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b06808
Abstract: Single-atom catalysts (SACs) and single-cluster catalysts (SCCs) are the new frontier of heterogeneous catalysis, which exhibit high activity, selectivity, stability, and atomic efficiency, as well as precise tunability. However, the lack of efficient methods for…
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Keywords:
single atom;
electrochemical potential;
high loading;
potential window ... See more keywords
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Published in 2018 at "Nature Communications"
DOI: 10.1038/s41467-018-04845-x
Abstract: Sub-nano metal clusters often exhibit unique and unexpected properties, which make them particularly attractive as catalysts. Herein, we report a “precursor-preselected” wet-chemistry strategy to synthesize highly dispersed Fe2 clusters that are supported on mesoporous carbon…
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Keywords:
chemistry;
epoxidation;
performance;
carbon nitride ... See more keywords
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Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d2cs00233g
Abstract: Multi-atom cluster catalysts have turned out to be novel heterogeneous catalysts with atomic dispersion for electrochemical energy applications. Beyond a simple combination of single-atom catalysts, they could offer boosted activity as a result of the…
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Keywords:
cluster catalysts;
atom cluster;
multi atom;
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Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc00953g
Abstract: This review explores the catalytic decomposition of ammonia into hydrogen, a critical process for sustainable hydrogen production. As ammonia rapidly emerges as the preferred carrier for hydrogen storage and transport, efficient decomposition methods are crucial…
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Keywords:
cluster catalysts;
metal;
single atom;
decomposition ... See more keywords