Stabilization of Re37+/Re38+ Metalloclusters by Cyanide Ligands in New Trinuclear Rhenium Cluster Complexes [{Re3X3}(CN)9]4-/[{Re3X3}(CN)9]5- (X = Br or I).
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00399
Abstract: The interaction of rhenium(III) halides Re3Br9 and Re3I9 with aqueous solution of sodium cyanide resulted in the formation of the first trinuclear halide-cyanide rhenium cluster complexes [{Re3X3}(CN)9]5-/[{Re3X3}(CN)9]4- (X = Br or I) crystallized as salts… read more here.
Keywords: rhenium cluster; cluster complexes; re3x3 re3x3; rhenium ... See more keywords
Improved Synthesis of (TBA)2[W6Br14] Paving the Way to Further Study of Bromide Cluster Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04426
Abstract: Octahedral cluster complexes of molybdenum and tungsten, [M6X8Y6]n- (M = Mo, W; X, Y = Cl, Br, I), are promising active components in various fields, including biomedicine and solar energy. Cluster complexes draw considerable attention… read more here.
Keywords: cluster complexes; bromide cluster; synthesis; cluster ... See more keywords
Synthetic and Structural Studies on Linear and Macrocyclic Pd- and Pt-Bridged Butterfly Fe/S Cluster Complexes
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00117
Abstract: Three types of (diphosphine)Pd- or Pt-bridged butterfly Fe/S cluster complexes have been prepared by a simple and convenient one-pot synthetic method. The first type of such complexes involves the linear (diphosphine)Pd- or Pt-bridged double-butterfly Fe/S… read more here.
Keywords: butterfly cluster; butterfly; cluster complexes; diphosphine ... See more keywords
Asymmetric Assembly of Chiral Lanthanide(III) Tetranuclear Cluster Complexes Using Achiral Mixed Ligands: Single-molecule Magnet Behavior and Magnetic Entropy Change
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c02155
Abstract: It is challenging to use achiral ligands to spontaneously construct chiral molecular magnets. In this work, two new Ln4 cluster complexes based on N,N′-(1,3-propanediyl)bis[N-[1,1-bis(hydroxymethyl)-2-hydroxyethyl]amine] (H6L) have been assembled, which are crystallized in a chiral space… read more here.
Keywords: single molecule; cluster complexes; molecule magnet;
DNA Modified with Boron–Metal Cluster Complexes [M(C2B9H11)2]—Synthesis, Properties, and Applications
Sign Up to like & getrecommendations! Published in 2018 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms19113501
Abstract: Together with tremendous progress in biotechnology, nucleic acids, while retaining their status as “molecules of life”, are becoming “molecular wires”, materials for the construction of molecular structures at the junction between the biological and abiotic… read more here.
Keywords: metal; cluster complexes; modified boron; dna modified ... See more keywords
Heteroctanuclear Au4Ag4 Cluster Complexes of 4,5-Diethynylacridin-9-One with Luminescent Mechanochromism
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27072127
Abstract: Two heteroctanuclear Au4Ag4 cluster complexes of 4,5-diethynylacridin-9-one (H2L) were prepared through the self-assembly reactions of [Au(tht)2](CF3SO3), Ag(tht)(CF3SO3), H2L and PPh3 or PPh2Py (2-(diphenylphosphino)pyridine). The Au4Ag4 cluster consists of a [Au4L4]4− and four [Ag(PPh3)]+ or [Ag(PPh2Py)]+… read more here.
Keywords: cluster complexes; heteroctanuclear au4ag4; au4ag4 cluster; diethynylacridin one ... See more keywords
Octahedral Rhenium Cluster Complexes with 1,2-Bis(4-pyridyl)ethylene and 1,3-Bis(4-pyridyl)propane as Apical Ligands
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27227874
Abstract: A series of eight new octahedral rhenium cluster complexes with the general formula trans-[{Re6Q8}L4X2] (Q = S or Se; L = 1,2-Bis(4-pyridyl)ethylene (bpe) or 1,3-Bis(4-pyridyl)propane (bpp); X = Cl or Br) was synthesized and investigated.… read more here.
Keywords: octahedral rhenium; cluster complexes; bis pyridyl;