Cluster Compounds with Oxidised, Hexanuclear [Nb6Cli 12Ia 6] n− Anions (n=2 or 3)
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DOI: 10.1002/open.202200063
Abstract: Abstract Four mixed‐halide cluster salts with chloride‐iodide‐supported octahedral Nb6 metal atoms cores were prepared and investigated. The cluster anions have the formula [Nb6Cli 12Ia 6] n− with Cl occupying the inner ligand sites and I… read more here.
Keywords: hexanuclear nb6cli; cluster compounds; oxidised hexanuclear; nb6cli 12ia ... See more keywords
Synthesis, crystal structure and transport properties of the cluster compounds Tl2Mo15S19 and Ag3Tl2Mo15S19
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DOI: 10.1016/j.materresbull.2020.111152
Abstract: We report the syntheses and crystal structures of the cluster compounds Tl2Mo15S19 and Ag3Tl2Mo15S19, two novel members of the series M2Mo15X19 (M = In, Tl, K, Rb, Cs, Ba; X = S, Se). While only… read more here.
Keywords: transport properties; cluster compounds; compounds tl2mo15s19; tl2mo15s19 ag3tl2mo15s19 ... See more keywords
Effect of Ag Doping on Electronic Structure of Cluster Compounds AgxMo9Se11 (x = 3.4, 3.9)
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DOI: 10.1021/acsaem.8b00718
Abstract: The electronic structure of AgxMo9Se11 as a potential material for thermoelectric applications was studied using high-energy-resolution fluorescence-detection X-ray absorption spectroscopy (HERFD-X... read more here.
Keywords: effect doping; structure cluster; electronic structure; doping electronic ... See more keywords
Derivatization of Phosphine Ligands with Bulky Deltahedral Zintl Clusters-Synthesis of Charge Neutral Zwitterionic Tetrel Cluster Compounds [(Ge9{Si(TMS)3}2)tBu2P]M(NHCDipp) (M: Cu, Ag, Au).
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DOI: 10.1021/jacs.7b05834
Abstract: Reactions of silylated clusters [Ge9{Si(TMS)3}3]- or [Ge9{Si(TMS)3}2]2- with dialkylhalophosphines R2PCl (Cy, iPr, tBu) at ambient temperature yield the first tetrel Zintl cluster compounds bearing phosphine moieties. Varying reactivity of the dialkylhalophosphines toward the silylated clusters… read more here.
Keywords: compounds ge9; ge9 tms; cluster compounds; cluster ... See more keywords