Organoamine-Directed Assembly of 5p-4f Heterometallic Cluster Substituted Polyoxometalates: Luminescence and Proton Conduction Properties.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02099
Abstract: The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p-4f heterometallic cluster substituted POMs were successfully isolated by a facile one-step… read more here.
Keywords: heterometallic cluster; substituted polyoxometalates; chemistry; assembly heterometallic ... See more keywords
{Ti6}/{Ti10} Wheel Cluster Substituted Silicotungstate Aggregates.
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DOI: 10.1021/acs.inorgchem.1c02788
Abstract: Two novel Ti-oxo wheel cluster substituted silicotungstates (STs) [H2N(CH3)2]9H9[Ti6O6(SiW10O37)3]·11H2O (1) and [H2N(CH3)2]16H10[Ti10O11(SiW10O37)2(SiW9O35)2]·14H2O (2) have been made by hydrothermal reactions. The polyoxoanion of 1 is a ring-shaped trimer where a Ti6O6 ({Ti6}) wheel cluster is encapsulated… read more here.
Keywords: siw10o37; wheel cluster; chemistry; cluster substituted ... See more keywords
Two rare Cr–Ln (Ln = Dy, Tb) heterometallic cluster substituted polyoxometalates featuring hexameric aggregates: hydrothermal syntheses, crystal structures and magnetic studies
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DOI: 10.1039/c8nj06327c
Abstract: Two hexameric Cr–Ln cluster substituted POMs have been obtained under hydrothermal conditions. They represent the first examples of 3d–4f heterometallic cluster substituted POMs incorporating Cr–Ln clusters. read more here.
Keywords: rare heterometallic; heterometallic cluster; cluster; substituted polyoxometalates ... See more keywords