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Published in 2017 at "Chemical Research in Chinese Universities"
DOI: 10.1007/s40242-017-6489-z
Abstract: The adsorption and decomposition mechanisms of methylamine catalyzed by Pt4 cluster supported on rutile(110) titania[namely, Pt4/TiO2-R(110)] were investigated via density functional theory slab calculations with Hubbard corrections(DFT+U). The adsorption energies under the most stable configuration…
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Keywords:
rutile 110;
methylamine decomposition;
decomposition;
cluster supported ... See more keywords
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Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc02552c
Abstract: Ligand exchange reactions of [Rh(COD){η4-Ge9(Hyp)3}] with L-type nucleophiles such as PMe3, PPh3, IMe4 (IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) or [W(Cp)2H2] result in the displacement of the COD ligand to afford clusters with coordinatively unsaturated trigonal pyramidal rhodium(i)…
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Keywords:
supported low;
exchange;
zintl cluster;
cluster supported ... See more keywords