Bimetallic Fe–Ir and Trimetallic Fe–Ir–Au Carbonyl Clusters Containing Hydride and/or Phosphine Ligands: Syntheses, Structures and DFT Studies
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DOI: 10.1007/s10876-020-01839-y
Abstract: The reaction of [HFe 4 (CO) 12 (IrCOD)] 2− ( 1 ) with CO at ambient conditions afforded [HFe 4 Ir(CO) 14 ] 2− ( 2 ), that, in turn, reacted with HBF 4 ·Et… read more here.
Keywords: pph; carbonyl clusters; trimetallic carbonyl; hfe ... See more keywords
Trinuclear clusters containing 2-aminopyridinate/pyrimidinate ligands as electrocatalysts for proton reduction
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DOI: 10.1016/j.jorganchem.2017.09.015
Abstract: Abstract Triiron and triruthenium clusters containing capping 2-aminopyridinate/pyrimidinate ligands are developed as functional models of the [FeFe]-hydrogenase for electrocatalytic reduction of protons to hydrogen. The 48-electron clusters Fe 3 (CO) 9 (μ 3 -pyNH)(μ-H) (… read more here.
Keywords: reduction; proton reduction; pyrimidinate ligands; aminopyridinate pyrimidinate ... See more keywords
Synthesis and Characterization of Ternary Clusters Containing the [As16]10- Anion, [MM'As16]4- (M = Nb or Ta; M' = Cu or Ag).
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DOI: 10.1021/acs.inorgchem.1c03940
Abstract: The [Nb@As8]3- anion was first isolated from solution in 1986, and a number of isostructural [M@Pn8]n- clusters (M = Nb, Cr, or Mo; Pn = As or Sb; n = 2 or 3) have since… read more here.
Keywords: chemistry; characterization ternary; synthesis characterization; clusters containing ... See more keywords
Quantum-Chemical Design of Molecular Structures of Tetra-, Penta- and Hexanuclear Metal Clusters Containing Aluminum and 3d-Element Atoms
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DOI: 10.3390/ma13081852
Abstract: Various data on the structural and thermodynamic characteristics of polynuclear metal clusters containing atoms of aluminum and various d-elements with the general formula AlnMm where (n + m) is 4, 5, or 6, and which… read more here.
Keywords: quantum chemical; metal; chemical design; element ... See more keywords