Rare-Earth and Antimony-Oxo Clusters Simultaneously Connecting Antimonotungstates Comprising Divacant and Tetravacant Keggin Fragments.
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DOI: 10.1021/acs.inorgchem.9b01570
Abstract: Four novel rare-earth (RE) and Sb-oxo clusters simultaneously bridging antimonotungstates (ATs) [H2N(CH3)2]8Na6H8{[RE4(H2O)6Sb6O4](SbW10O37)2(SbW8O31)2}·24H2O [RE = Dy3+ (1), Er3+ (2), Y3+ (3), Ho3+ (4)] were triumphantly isolated by using Na9[B-α-SbW9O33]·19.5H2O, dimethylamine hydrochloride, SbCl3, and RE(NO3)3·6H2O in acidic… read more here.
Keywords: oxo clusters; energy; rare earth; clusters simultaneously ... See more keywords