Mixed-Isocyanide Complexes of Technetium under Steric and Electronic Control.
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DOI: 10.1021/acs.inorgchem.2c02730
Abstract: Reactions of the alkyl isocyanide fac-[Tc(CO)3(CNR)2Cl] complexes (2) (CNR = CNnBu or CNtBu) with the sterically encumbered isocyanide CNp-FArDarF2 [DArF = 3,5-(CF3)2C6H3] allow a selective exchange of the carbonyl ligands of 2 and the isolation… read more here.
Keywords: technetium; isocyanide; cnp fardarf2; isocyanide complexes ... See more keywords