Supramolecular association involving nitrile–nitrile interactions in polymeric Mn(II) coordination complexes: A combined experimental and theoretical study
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.12.055
Abstract: Abstract Two new Mn(II) coordination polymers viz. [Mn(p-NBz)2(4-CNpy)2]n (1) and [Mn(4-CNpy)2(H2BTC)2]n (2) [p-NBz = p-nitrobenzoate, H3BTC = 1,3,5-benzenetricarboxylic acid and 4-CNpy = 4-cyanopyridine] have been synthesized at room temperature and characterized by single crystal X-ray diffraction, FT-IR spectroscopy, electronic spectroscopy, elemental… read more here.
Keywords: spectroscopy; nitrile nitrile; cnpy; coordination ... See more keywords
4-Cyanopyridine, a versatile mono- and bidentate ligand. Crystal structures of related coordination polymers determined by X-ray powder diffraction
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce00425g
Abstract: 4-Cyanopyridine (4-CNpy, also known as isonicotinonitrile) can act as a monodentate ligand in transition metal complexes via the pyridine nitrogen atom (Npy), or as a bidentate ligand via both nitrogen atoms (Npy and NCN), resulting… read more here.
Keywords: cnpy; bidentate ligand; cyanopyridine; metal ... See more keywords
4-Cyanopyridine complexes [MX2(4-CNpy)x]n (with X = Cl, Br and x = 1, 2): crystal structures, thermal properties and a comparison with [MX2(3-CNpy)x]n complexes
Sign Up to like & getrecommendations! Published in 2020 at "CrystEngComm"
DOI: 10.1039/c9ce02012h
Abstract: Eleven new complexes [MX2(4-CNpy)x](n) with M = Mn, Fe, Co, Ni, Cu, and Zn, X = Cl and Br, 4-CNpy = 4-cyanopyridine, and x = 1 and 2 have been prepared and their structures were… read more here.
Keywords: cnpy; mx2 cnpy; complexes mx2; metal atoms ... See more keywords