Waste Recycling: Ionic Liquid-Catalyzed 4-Electron Reduction of CO2 with Amines and Polymethylhydrosiloxane Combining Experimental and Theoretical Study
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DOI: 10.1021/acssuschemeng.8b02352
Abstract: The acetate-based ionic liquids (ILs), e.g., [nBu4N]OAc, have been developed for challenging 4-electron reduction of CO2 with amines and hydrosilane to afford aminals. Notably, polymethylhydrosiloxane, a cheap byproduct of the silicone industry, also works well… read more here.
Keywords: electron reduction; reduction co2; study; electron ... See more keywords
Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines
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DOI: 10.1021/acssuschemeng.8b03245
Abstract: Transformation of carbon dioxide (CO2) into valuable chemicals is of great importance, and development of novel and efficient catalysts is crucial. Herein, we found that the renewable lecithin could be used as an efficient organocatalyst… read more here.
Keywords: efficient organocatalyst; formamides methylamines; co2; biocompatible lecithin ... See more keywords