Photoswitchable Cu(ii)/Cu(i) catalyses assisted by enzyme-like non-covalent interactions in Cu(ii)–melamine coordination polymers for installing CO2/CS2 and CF3 groups in heterocycles
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DOI: 10.1039/d0nj02154g
Abstract: Despite concerns over the environmental impact of isoelectronic CO2 and CS2, they remain useful C1 building blocks with industrial utility, and trifluoromethylation could enhance the lipophilicity and metabolic stability of agrochemicals and pharmaceuticals. Merging the… read more here.
Keywords: enzyme like; like non; cs2; co2 cs2 ... See more keywords
Insertion of CO2 and CS2 into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer
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DOI: 10.1039/d3sc01635h
Abstract: The uptake and release of small molecules continue to be challenging tasks of utmost importance in synthetic chemistry. The combination of such small molecule activation with subsequent transformations to generate unusual reactivity patterns opens up… read more here.
Keywords: light induced; catalyzed activation; co2 cs2; co2 ... See more keywords