Strong Electronic Metal–Support Interaction between Iridium Single Atoms and a WO3 Support Promotes Highly Efficient and Robust CO2 Cycloaddition
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202206991
Abstract: The carbon dioxide (CO2) cycloaddition of epoxides to cyclic carbonates is of great industrial importance owing to the high economical values of its products. Single‐atom catalysts (SACs) have great potential in CO2 cycloaddition by virtue… read more here.
Keywords: co2; co2 cycloaddition; single atoms; wo3 support ... See more keywords
Synergistic Dual‐Active Sites Engineering in ZIF‐Derived CoOx/B‐Modified g‐C3N4 for Efficient CO2 Cycloaddition Under Mild Conditions
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202500759
Abstract: The carbon dioxide (CO2) cycloaddition reaction provides an efficient route to achieve resource utilization of CO2. However, the inherent chemical stability of CO2 itself hinders its efficient transformation into cyclic carbonates. Herein, the CoOx/BCN catalyst… read more here.
Keywords: reaction; co2; coox bcn; co2 cycloaddition ... See more keywords
A MOF@MOF S-scheme Heterojunction with Lewis Acid-Base Sites Synergistically Boosts Cocatalyst-Free CO2 Cycloaddition.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202401362
Abstract: The photocatalytic cycloaddition reaction between CO2 and epoxide is one of the most promising green routes for CO2 utilization, for which high performance photocatalysts are intensely desired. Herein, we have constructed an S-scheme heterojunction of… read more here.
Keywords: spectroscopy; co2 cycloaddition; scheme heterojunction; lewis acid ... See more keywords
Highly Exposed NH2 Edge on Fragmented g-C3 N4 Framework with Integrated Molybdenum Atoms for Catalytic CO2 Cycloaddition: DFT and Techno-Economic Assessment.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202204336
Abstract: This study focuses on the applicability of single-atom Mo-doped graphitic carbon nitride (GCN) nanosheets which are specifically engineered with high surface area (exfoliated GCN), NH2 rich edges, and maximum utilization of isolated atomic Mo for… read more here.
Keywords: co2; mo2 gcn; co2 cycloaddition; techno economic ... See more keywords
CO2 cycloaddition with propylene oxide to form propylene carbonate on a copper metal-organic framework: A density functional theory study
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2018.11.015
Abstract: Abstract Metal-organic frameworks (MOFs) have emerged as unique catalysts for CO2 conversion, but the catalytic mechanism remains elusive. In this study, a density functional theory (DFT) study is reported on CO2 cycloaddition with propylene oxide… read more here.
Keywords: co2 cycloaddition; propylene; study; metal organic ... See more keywords
Dynamic Metal-Iodide Bonds in a Tetracoordinated Cadmium-Based Metal-Organic Framework Boosting Efficient CO2 Cycloaddition under Solvent- and Cocatalyst-Free Conditions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00569
Abstract: Due to the inherent thermodynamic stability and kinetic inertness of CO2, heterogeneous catalytic conversion of CO2 to cyclic carbonates often requires harsh operating conditions, high temperature and high pressure, and the addition of cocatalysts. Therefore,… read more here.
Keywords: mof; efficient co2; co2 cycloaddition; cocatalyst free ... See more keywords
Cooperative 3-Pyridonate-Functionalized Zinc(II) Imidazolium Catalysts for CO2 Cycloaddition to Challenging Epoxides at Ambient Conditions: A Pathway to Renewable Cyclic Carbonates.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04220
Abstract: Two zwitterionic 3-pyridonate-functionalized tetrahedral zinc(II) imidazolium complexes (3 and 4) were synthesized and characterized thoroughly by various spectroscopic techniques. They consist of the pendant imidazolium group with potential hydrogen bonding sites, invoking a metal-ligand cooperativity… read more here.
Keywords: co2 cycloaddition; zinc imidazolium; zinc; pyridonate functionalized ... See more keywords
Atomically Dispersed Dual Metal Sites Boost the Efficiency of Olefins Epoxidation in Tandem with CO2 Cycloaddition.
Sign Up to like & getrecommendations! Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.2c03087
Abstract: Tandem catalysis provides an economical and energy-efficient process for the production of fine chemicals. In this work, we demonstrate that a rationally synthesized carbon-based catalyst with atomically dispersed dual Fe-Al sites (ADD-Fe-Al) achieves superior catalytic… read more here.
Keywords: atomically dispersed; dual metal; metal sites; co2 cycloaddition ... See more keywords
Multifunctional Catalytic Surface Design for Concerted Acceleration of One-Pot Hydrosilylation-CO2 Cycloaddition.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b03602
Abstract: Silica-supported Rh-ammonium iodide catalyst showed high performance for hydrosilylation-CO2 cycloaddition reaction sequences. The catalyst was prepared by surface grafting of Rh and the silane-coupling reaction of the ammonium iodide moiety. The acceleration of each catalytic… read more here.
Keywords: co2 cycloaddition; hydrosilylation co2; reaction;
Iron Located on a Hollow Support Constructed with a Polymer-Assisted Template for Enhancing CO2 Cycloaddition.
Sign Up to like & getrecommendations! Published in 2025 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.5c19886
Abstract: Hollow carbon nanocages derived from postmodified metal-organic frameworks (PM-MOFs) exhibit a controllable morphology, excellent thermal stability, and a high specific surface area, making them promising candidates for heterogeneous catalysis. Herein, we employ a polymer-assisted strategy… read more here.
Keywords: co2 cycloaddition; iron located; polymer assisted; polymer ... See more keywords
Unprecedented NH2-MIL-101(Al)/n-Bu4NBr system as solvent-free heterogeneous catalyst for efficient synthesis of cyclic carbonates via CO2 cycloaddition.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt03754f
Abstract: Amine-functionalised framework NH2-MIL-101(Al) was synthesized using a solvothermal and microwave method and characterized by PXRD, FT-IR, TGA, SEM-EDX, and BET surface area analysis. The desolvated framework, in the presence of co-catalyst tetrabutylammonium bromide (TBAB), acted… read more here.
Keywords: nh2 mil; cycloaddition; co2 cycloaddition; co2 ... See more keywords