Indium-Catalyzed CO2/Epoxide Copolymerization: Enhancing Reactivity with a Hemilabile Phosphine Donor.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03123
Abstract: Group 13 metal complexes have emerged as powerful catalysts for transforming CO2 into added-value products. However, direct comparisons of reactivity between Al, Ga, and In catalysts are rare. We report aluminum (1), gallium (2), and… read more here.
Keywords: co2 epoxide; hemilabile phosphine; indium; phosphine ... See more keywords
Catalytic coupling of CO2 with epoxide by metal macrocycles functionalized with imidazolium bromide: insights into the mechanism and activity regulation from density functional calculations.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04684k
Abstract: The cycloaddition of CO2 and epoxide catalysed by metalloporphyrins (IL-M(TPP)) and metallocorroles (IL-M(Cor)) containing imidazolium bromide has been studied extensively using density functional theory calculations. Possible mechanisms and catalytic effects of the hydrogen substitution on… read more here.
Keywords: metal; co2 epoxide; density functional; imidazolium bromide ... See more keywords