Highly Efficient Catalysts for CO2 Fixation using Guanidinium‐Functionalized Zr‐MOFs
Sign Up to like & getrecommendations! Published in 2023 at "ChemCatChem"
DOI: 10.1002/cctc.202300079
Abstract: An effective approach for tuning CO2 adsorption, activation and transformations of various epoxides in CO2 fixation reactions is introducing functional groups into the pores of metal‐organic frameworks (MOFs) through ligand modification. Herein, a novel ionic… read more here.
Keywords: catalysts co2; highly efficient; efficient catalysts; co2 fixation ... See more keywords
4‐Aminopyridines as Versatile “Noninterfering” Allies for CO2 Fixation
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202501150
Abstract: Organic superbases are a family of compounds endowed with high nucleophilicity and basicity. Several powerful nucleophiles such as DBU (1,8‐diazabicyclo[5.4.0]undec‐7‐ene), TBD (1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene), or DMAP (4‐dimethylaminopyridine) are involved in CO2 conversion but their catalytic roles may… read more here.
Keywords: versatile noninterfering; noninterfering allies; co2 fixation; allies co2 ... See more keywords
Divergent CO2 Fixation Modes by Aluminum‐Base Bimetallic Systems: Mechanism Investigations
Sign Up to like & getrecommendations! Published in 2025 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202500379
Abstract: The conversion and utilization of carbon dioxide (CO2) is a challenging contemporary issue in the present day, and the first step is the CO2 fixation. Recently, the main group metal compounds have been found that… read more here.
Keywords: divergent co2; bond; bond mode; fixation modes ... See more keywords
Structural Modulation in Viologen‐Based Ionic Porous Organic Polymers for Catalytic Non‐Redox CO2 Fixation
Sign Up to like & getrecommendations! Published in 2025 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.202400373
Abstract: The rational design of metal‐free, porous, and heterogeneous catalysts with large specific surface areas for efficient CO2 capture and utilization has remained a significant challenge. In this study, two structurally distinct viologen‐based novel ionic porous… read more here.
Keywords: ionic porous; co2; organic polymers; porous organic ... See more keywords
Synthesis of cyclic carbonate by CO2 fixation to epoxides using interpenetrated MOF-5/n-Bu4NBr
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Science"
DOI: 10.1007/s10853-019-03702-6
Abstract: Phase-pure interpenetrated MOF-5 ([Zn4(O)(BDC)3]) was synthesized by pH* control in a reaction medium, and its stability in the presence of epoxides was confirmed by powder X-ray diffraction analysis. Interpenetrated MOF-5/tetra-n-butylammonium bromide (int-MOF-5/n-Bu4NBr) showed a high… read more here.
Keywords: co2; mof bu4nbr; interpenetrated mof; co2 fixation ... See more keywords
Room temperature CO2 fixation via cyclic carbonate synthesis over vanadium-MOF catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Korean Journal of Chemical Engineering"
DOI: 10.1007/s11814-019-0255-5
Abstract: Vanadium containing 3D MOF, MIL-47 displayed excellent synergistic catalysis with alkyl ammonium halides (TBAX) in the room temperature fixation of CO2. Theoretical intrinsic-reaction-coordinate calculations were performed at the level of M06/LACVP**++ implemented in Jaguar v8.5… read more here.
Keywords: fixation; mof; co2 fixation; room temperature ... See more keywords
Concurrent enhancement of CO2 fixation and productivities of omega-3 fatty acids and astaxanthin in Haematococcus pluvialis culture via calcium-mediated homeoviscous adaptation and biomineralization.
Sign Up to like & getrecommendations! Published in 2021 at "Bioresource technology"
DOI: 10.1016/j.biortech.2021.125720
Abstract: Haematococcus pluvialis has attracted interest as a bio-platform for producing omega-3 fatty acids (ω-3 FA) and astaxanthin that have a great potential as anti-inflammatory drugs. This study aimed to concurrently enhance the CO2 fixation and… read more here.
Keywords: homeoviscous adaptation; adaptation biomineralization; co2 fixation; culture ... See more keywords
Chlorella vulgaris phycoremediation at low Cu+2 contents: Proteomic profiling of microalgal metabolism related to fatty acids and CO2 fixation.
Sign Up to like & getrecommendations! Published in 2021 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2021.131272
Abstract: The aim of this work was to correlate metabolic changes with copper ions (Cu+2) bioremediation by microalgae C. vulgaris 097 CCMA-UFSCar at low Cu+2 content. The metabolic effects include proteome changes related to fatty acid… read more here.
Keywords: fixation; related fatty; metabolism related; co2 fixation ... See more keywords
Polybenzoxazine intrinsically installed N-methylpyridinium iodide functions efficient organocatalyst for CO2 fixation into cyclic carbonate
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110397
Abstract: Abstract Polybenzoxazine containing N-methylpyridinium iodide (PBz-[PyMe]I) was first utilized as an efficient catalyst for CO2 fixation into cyclic carbonates. The polymer structure was determined as a phenolic-type polybenzoxazine characterized by FT-IR, 1H NMR. PBz-[PyMe]I shows… read more here.
Keywords: co2; polybenzoxazine; methylpyridinium iodide; co2 fixation ... See more keywords
Soil microbial anaplerotic CO2 fixation in temperate soils
Sign Up to like & getrecommendations! Published in 2019 at "Geoderma"
DOI: 10.1016/j.geoderma.2018.08.014
Abstract: Abstract In soils both δ13C and δ15N values of soil organic matter (SOM) tend to increase with soil depth. This change in soil C and N isotopic composition is at least partially linked to soil… read more here.
Keywords: co2; fixation; anaplerotic co2; co2 fixation ... See more keywords
Combination of brewery wastewater purification and CO2 fixation with potential value-added ingredients production via different microalgae strains cultivation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2020.122332
Abstract: Abstract Microalgae have the advantages of eco-friendly and cost-effective for wastewater and flue gas purification. In this work, four different microalgae strains (Chlorella sp. L166, Chlorella sp. UTEX1602, Scenedesmus sp. 336 and Spirulina sp. FACHB-439)… read more here.
Keywords: brewery wastewater; wastewater; wastewater purification; co2 fixation ... See more keywords