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   Articles with "co2 formate" as a keyword



Modulating the Hydrogenation Mechanism of Electrochemical CO2 Reduction Using Ruthenium Atomic Species on Bismuth

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recommendations! Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202405835

Abstract: The conversion of CO2 into formate through electrochemical methods is emerging as an elegant approach for industrial‐scale CO2 utilization in the near future. Although Bismuth (Bi)‐based materials have shown promise thank to their excellent selectivity,… read more here.

Keywords: atomic species; ruthenium atomic; hydrogenation; co2 ... See more keywords

Fibrous Pb(II)‐Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High‐Rate, Selective CO2‐to‐Formate Conversion

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recommendations! Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202417223

Abstract: A nonporous [Pb(tadt)]n (tadt = 1,3,4‐thiadiazole‐2,5‐dithiolate) coordination polymer, KGF‐9, with a 2D infinite (−Pb−S−)n structure has been previously reported as a precious‐metal‐free photocatalyst for selective CO2‐to‐formate conversion under visible light. In the present work, a… read more here.

Keywords: co2 formate; formate; coordination polymer; formate conversion ... See more keywords

Oxygen‐Pinned Ag1In Single‐Atom Alloy for Efficient Electroreduction CO2 to Formate

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recommendations! Published in 2024 at "Advanced Energy Materials"

DOI: 10.1002/aenm.202400813

Abstract: Catalytic conversion of CO2 to valuable formate provides a pathway to carbon neutrality. Indium (In), as a promising catalyst, exhibits high selectivity toward formate due to its suitable bonding ability of *OCHO intermediates. However, it… read more here.

Keywords: co2; formate; oxygen pinned; single atom ... See more keywords

Prototype Validation of a Large‐Scale CO2‐to‐Formate Zero‐Gap Electrolyzer

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recommendations! Published in 2025 at "Chemsuschem"

DOI: 10.1002/cssc.202501116

Abstract: The scale‐up of gas‐phase CO2 electroreduction to formate is crucial for its industrial application but remains largely unexplored. This work presents the design and validation of a 100 cm2 electrolyzer prototype featuring a zero‐gap configuration and… read more here.

Keywords: zero gap; co2; prototype; scale ... See more keywords

Interfacial Electronic Interaction in Amorphous-Crystalline CeOx -Sn Heterostructures for Optimizing CO2 to Formate Conversion.

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recommendations! Published in 2024 at "Small"

DOI: 10.1002/smll.202400191

Abstract: Formate, a crucial chemical raw material, holds significant promise for industrial applications in the context of CO2 electroreduction reaction (CO2 RR). Despite its potential, challenges, such as poor selectivity and low formation rate at high… read more here.

Keywords: ceox; crystalline ceox; ceox heterostructures; crystalline ... See more keywords

Bismuth coated graphite felt modified by silver particles for selective electroreduction of CO2 into formate in a flow cell

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recommendations! Published in 2021 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2021.137821

Abstract: A 3D porous Ag-Bi electrode was developed to achieve the highly selective reduction of CO2 into formate. Ag particles were deposited on Bi coated graphite felt by galvanic displacement reaction. The selectivity of the reduction… read more here.

Keywords: graphite felt; coated graphite; co2 formate; bismuth coated ... See more keywords

Indium-Based Metal-Organic Framework for High-Performance Electroreduction of CO2 to Formate.

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recommendations! Published in 2020 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.0c00769

Abstract: It is urgent to find a catalyst with high selectivity and efficiency for the reduction of CO2 by renewable electric energy, which is the important means to reduce the greenhouse effect. In this work, we… read more here.

Keywords: indium based; metal organic; co2; metal ... See more keywords

Design Strategy toward Recyclable and Highly Efficient Heterogeneous Catalysts for the Hydrogenation of CO2 to Formate

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recommendations! Published in 2018 at "ACS Catalysis"

DOI: 10.1021/acscatal.8b00392

Abstract: One bottleneck in the realization of CO2 conversion into value-added compounds is the lack of catalysts with both excellent activity and recyclability. Herein, a catalyst is designed for the hydrogenation of CO2 to formate to… read more here.

Keywords: hydrogenation co2; hydrogenation; co2; co2 formate ... See more keywords
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Ultrathin tin monosulfide nanosheets with the exposed (001) plane for efficient electrocatalytic conversion of CO2 into formate†

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recommendations! Published in 2020 at "Chemical Science"

DOI: 10.1039/c9sc06548b

Abstract: Current Sn-based materials are ideal catalysts developed to drive the electrochemical conversion of CO2 to formate, but competing proton reduction to hydrogen is an ever-present drain on catalytic selectivity. Herein, we report a reliable electrochemical… read more here.

Keywords: conversion co2; sns nss; formate; co2 formate ... See more keywords

Controlled synthesis of hierarchical Bi nanostructures by electrodeposition for selective electroreduction of CO2 to formate.

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recommendations! Published in 2025 at "Nanoscale"

DOI: 10.1039/d5nr02832a

Abstract: The electrocatalytic conversion of CO2 into formate represents a promising strategy for carbon-neutral energy cycles. Critical to this process is the controlled synthesis of highly active and selective catalysts, enabling sustained high energy efficiency under… read more here.

Keywords: co2 formate; synthesis; synthesis hierarchical; controlled synthesis ... See more keywords

High Throughput Preparation of Bi-Sb Alloy Films for the Electrocatalytic Reduction of CO2 to Formate

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recommendations! Published in 2023 at "Journal of The Electrochemical Society"

DOI: 10.1149/1945-7111/acd4eb

Abstract: Bi is considered a highly active and selective electrocatalyst for CO2 reduction reaction (CO2RR), and Sb has great development potential. In this study, we fabricated a series of Bi-Sb alloy films by magnetron co-sputtering and… read more here.

Keywords: reduction; formate; co2 formate; alloy films ... See more keywords