C-Methylenation of anilines and indoles with CO2 and hydrosilane using a pentanuclear zinc complex catalyst.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc03675k
Abstract: The one-step C-methylenation of anilines and indoles with CO2 and phenylsilane was catalyzed by a pentanuclear ZnII complex to give diarylmethanes via geminal C-H and C-C bond formation. It is proposed that the zinc-hydride complex… read more here.
Keywords: hydrosilane using; anilines indoles; co2 hydrosilane; indoles co2 ... See more keywords