Hydrogenation of CO2 to Methanol with Mn‐PNP‐Pincer Complexes in the Presence of Lewis Acids: the Formate Resting State Unleashed
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DOI: 10.1002/cctc.202100649
Abstract: The hydrogenation of CO2 to methanol was achieved using a catalytic system comprising metal complexes of the form [Mn(CO)2[N(C2H4PR2)] (R=iPr/Ph, [HN(C2H4PPh2)2]=MACHO−Ph) together with Lewis acid additives. Mechanistic studies suggest initial CO2 insertion into a Mn−H… read more here.
Keywords: co2; resting state; hydrogenation co2; co2 methanol ... See more keywords
Use of an optofluidic microreactor and Cu nanoparticles synthesized in ionic liquid and embedded in TiO2 for an efficient photoreduction of CO2 to methanol
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DOI: 10.1016/j.cej.2020.126643
Abstract: Abstract The slow kinetics in the photocatalytic reduction of CO2, as well as the low quantum efficiencies achieved, directly related to the photocatalyst and reactor configuration applied, limit the widespread use of this technology. In… read more here.
Keywords: co2; ionic liquid; optofluidic microreactor; co2 methanol ... See more keywords
Plasmonic gold deposited on mesoporous Ti Si1−O2 with isolated silica in lattice: An excellent photocatalyst for photocatalytic conversion of CO2 into methanol under visible light irradiation
Sign Up to like & getrecommendations! Published in 2018 at "Journal of CO2 Utilization"
DOI: 10.1016/j.jcou.2018.06.016
Abstract: Abstract Solar-driven chemical production of methanol from CO2 has become a hot topic of research due to high-value addition, with methanol as a product, as well as reduction of CO2 which is a greenhouse gas.… read more here.
Keywords: microscopy; methanol; deposited mesoporous; co2 ... See more keywords
Mechanistic study of Cu-Ni bimetallic catalysts supported by graphene derivatives for hydrogenation of CO2 to methanol
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DOI: 10.1016/j.jcou.2021.101542
Abstract: Abstract The Cu-Ni bimetallic catalyst supported by graphene derivatives was employed to explore the reaction mechanisms of converting CO2 to methanol. Their properties were analyzed by Raman, XRD, XPS, TG-DSC, TEM and CO2-TPD. Cu or… read more here.
Keywords: graphene derivatives; co2; co2 methanol; mechanistic study ... See more keywords
Synthesis of Ni2P/CdS and Pt/TiO2 nanocomposite for photoreduction of CO2 into methanol
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DOI: 10.1038/s41598-021-87625-w
Abstract: It is a great challenge to convert thermochemically stable CO2 into value-added products such as CH4, CH3OH, CO via utilizing solar energy. It is also a difficult task to develop an efficient catalyst for the… read more here.
Keywords: co2; ni2p cds; cds tio2; synthesis ni2p ... See more keywords
A theoretical study on the hydrogenation of CO2 to methanol catalyzed by ruthenium pincer complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01352e
Abstract: Herein, a density functional theory (DFT) study was performed to investigate thoroughly the cascade reaction mechanism for the hydrogenation of carbon dioxide to methanol catalyzed by ruthenium pincer complex [RuH2(Me2PCH2SiMe2)2NH(CO)]. Three catalytic stages involving the… read more here.
Keywords: hydrogenation; hydrogenation co2; co2 methanol; ruthenium pincer ... See more keywords