From Small Metal Clusters to Molecular Nanoarchitectures with a Core–Shell Structure: The Synthesis, Redox Fingerprint, Theoretical Analysis, and Solid-State Structure of [Co38As12(CO)50]4–
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DOI: 10.1021/acs.inorgchem.2c00506
Abstract: The cluster [Co38As12(CO)50]4– was obtained by pyrolysis of [Co6As(CO)16]−. The metal cage features a closed-packed core inside a Co/As shell that progressively deforms from a cubic face-centered symmetry. The redox and acid–base reactivities were determined… read more here.
Keywords: structure; co38as12; redox; small metal ... See more keywords