A tetra Co(II/III) complex with an open cubane Co4O4 core and square-pyramidal Co(II) and octahedral Co(III) centres: bifunctional electrocatalytic activity towards water splitting at neutral pH.
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DOI: 10.1039/d1dt04086c
Abstract: The reaction of 2,6-diformyl-4-methylphenol, 4-methoxybenzoylhydrazine and Co(OAc)2·4H2O in 1 : 2 : 2 mole ratio in methanol under aerobic conditions produced in 61% yield a tetranuclear complex having the molecular formula [CoIICoIII(μ-OAc)(μ3-OH)(μ-L)]2 where OAc- and L3- represent acetate and… read more here.
Keywords: electrocatalytic activity; co4o4; square pyramidal; iii ... See more keywords