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Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01709
Abstract: Direct phosphorylation of enamine and enamide with hydrogen evolution was realized via cobaloxime catalysis under visible-light irradiation. Control experiments and spectroscopic studies demonstrated a reductive quenching pathway of cobaloxime catalyst to produce phosphinoyl radical, which…
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Keywords:
phosphorylation;
hydrogen evolution;
cobaloxime catalysis;
enamine ... See more keywords