Cobaloxime Catalysis for Enamine Phosphorylation with Hydrogen Evolution.
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DOI: 10.1021/acs.orglett.0c01709
Abstract: Direct phosphorylation of enamine and enamide with hydrogen evolution was realized via cobaloxime catalysis under visible-light irradiation. Control experiments and spectroscopic studies demonstrated a reductive quenching pathway of cobaloxime catalyst to produce phosphinoyl radical, which… read more here.
Keywords: phosphorylation; hydrogen evolution; cobaloxime catalysis; enamine ... See more keywords